Optical rotation of achiral pentaerythritol

Claborn K, Cedres JH, Isborn C, Zozulya A, Weckert E, Kaminsky W, Kahr B. Optical rotation of achiral pentaerythritol. Journal of the American Chemical Society. 2006;128(46):14746–14747.

Abstract

The optical rotatory power of achiral crystals of achiral pentaerythritol molecules was measured. The maximum rotations were found to be +/-6 degrees /mm. The quantum mechanically computed rotation of pentaerythritol molecules using linear response theory was 6 times larger although the experimental and theoretical tensors were similarly oriented to within 5 degrees .
Last updated on 07/25/2022